郭灿城 - 湖南大学 - 化学化工学院

研究领域

仿生催化；生物物理有机化学；功能有机合成 1981年本科毕业于湖南师范大学化学系，1988年研究生毕业于南开大学化学系，硕士学位。1994年晋升教授，1997年遴选为博士生导师，1999年享受国务院政府特殊津贴，2004年入选湖南省新世纪121人才工程第一层次人选。1997.11-2000.6任湖南大学化学化工学院总支书记，2000.6-2011.3任湖南大学化学化工学院院长。

近期论文

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Mingzhong Zhang, Wenbing Sheng, Qing Jiang, Mi Tian, Yong Yin, and Cancheng Guo*, Metal-Free Synthesis of Oxindoles via (NH4)2S2O8‑Mediated Halocarbocyclization of Alkenes in Water. J. Org. Chem. 2014, 79, 10829 Qing Jiang, Jing-Yu Wang, and Cancheng Guo*, Iodine(III)-Mediated C−H Alkoxylation of Aniline Derivatives with Alcohols under Metal-Free Conditions. J. Org. Chem. 2014, 79, 8768 Qing Jiang, Bin Xu, An Zhao, Jing Jia, Tian Liu, and Cancheng Guo*, Transition-Metal-Free Oxidative α‑C−H Amination of Ketones via a Radical Mechanism: Mild Synthesis of α‑Amino Ketones. J. Org. Chem. 2014, 79, 8750 Qing Jiang, Bin Xu, Jing Jia, An Zhao, Yurou Zhao, Yingying Li, Nana He, and Cancheng Guo*, Copper-Catalyzed Aerobic Decarboxylative Sulfonylation of Cinnamic Acids with Sodium Sulfinates: Stereospecific Synthesis of (E)‑Alkenyl Sulfones. J. Org. Chem. 2014, 79, 7372 Qing Jiang, An Zhao, Bin Xu, Jing Jia, Xin Liu, and Cancheng Guo*, PIFA-Mediated Esterification Reaction of Alkynes with Alcohols via Oxidative Cleavage of Carbon Triple Bonds. J. Org. Chem. 2014, 79, 2709 Wen-Bing Sheng, Qing Jiang, Wei-Ping Luo, and Can-Cheng Guo*. Oxidative Rearrangement of Internal Alkynes To Give One-Carbon-Shorter Ketones via Manganese Porphyrins Catalysis. J. Org. Chem. 2013, 78, 5691. Jin-Hui Xu, Qing Jiang, and Can-Cheng Guo*. Phenyliodonium Diacetate Mediated Direct Synthesis of Benzonitriles from Styrenes through Oxidative Cleavage of C=C Bonds. J. Org. Chem. 2013, 78, 11881 Kelai Li, Zongbo Du, Cancheng Guo,* and Qingyun Chen*，Regioselective Syntheses of 2- and 4-Formylpyrido[2,1-b]benzoxazoles. J. Org. Chem. 2009, 74, 3286. Chao Liu, Dongmei Shen, Zhuo Zeng, Cancheng Guo* and Qingyun Chen*, C-F Bond Activation by Modified Sulfinatodehalogenation: Facile Synthesis and Properties of Novel Tetrafluorobenzoporphyrins by Direct Intramolecular Cyclization and Reductive Defluorinative Aromatization of Readily Available β-Perfluoroalkylated Porphyrins. J. Org. Chem. 2006, 71, 9772. Limei Jin, Liang Chen, Juanjuan Yin, Jinming Zhou, Cancheng Guo*, and Qingyun Chen*. Rational Synthesis of meso- or a- Fluoroalkylporphyrin Derivatives via Halo-fluoroalkylporphyrin Precursors: Electronic and Steric Effects on Regioselective Electrophilic Substitution in 5-Fluoroalkyl-10,20-diarylporphyrins. J. Org. Chem. 2006, 71, 527. Limei Jin, Zhuo Zeng, Cancheng Guo*, Qingyun Chen*, Fluoroalkylation of Porphyrins: Synthesis and Reactions of β-Fluoroalkyltetraarylporphyrins. J. Org. Chem. 2003, 68, 3912-1917 Kelai Li, Cancheng Guo* and Qingyun Chen*, Unprecedented Degradation of Nickel(II) 2,3,12,13-Tetrabromo-5,10,15,20-tetraarylporphyrins by the Anion of E-Benzaldoxime: A Novel Approach to Nickel(II) Chlorophins and Bacteriophins. Org. Lett. 2009, 11, 2724 Chang-Di Chen, Wen-Bing Sheng, Guo-Jun Shi and Can-Cheng Guo*. Substituent-induced regioselective hydroxylation of the aromatic C–H bond on naphthalene with metachloroperbenzoic acid catalyzed by F20TPPMnCl. J. Phy. Org. Chem. 2013, 26, 23 Linjian Zhu, Jian Wang, Tiegang Reng, Chunyan Li, Dongcai Guo, Cancheng Guo*. Effect of substituent groups of porphyrins on the electroluminescent properties of porphyrin-doped OLED devices. J. Phy. Org. Chem. 2010, 23, 190 Qing Jiang, Wenbing Sheng, Mi Tian, Jie Tang, and Cancheng Guo*. Cobalt(II)–Porphyrin-Catalyzed Aerobic Oxidation: Oxidative Coupling of Phenols. Eur. J. Org. Chem. 2013, 1861-1866 Cancheng Guo*, Rongbiao Tong and Kelai Li，Chloroalkyl Piperazine and Nitrogen Mustard Porphyrins: Synthesis and Anticancer Activity，Bioorg Med Chem 2004, 12，2469-2475 Cancheng Guo*, Heping Li and Xiaobing Zhang，Study on synthesis, characterization and biological activity of some new nitrogen heterocycle porphyrins. Bioorg Med Chem, 2003, 11, 1745-1751 Wukun Liu, Chaozhou Liu, Changjun Gong, Weiying Lin, Cancheng Guo*, Porphyrins containing nitric oxide donors: Synthesis and cancer cell-oriented NO release. Bioorg Med Chem Lett, 2009, 19, 1647 Cancheng Guo *, Heping Li, Jianbing Xu，Synthesis of μ-oxo-bismanganeseporphyrin compounds and their catalysis for cyclohexane hydroxylation. J Catal, 1999, 185, 345-351 Cancheng Guo *. Synthesis of μ-oxo-bisironporphyrin compounds and their catalysis for cyclohexane hydroxylation. J Catal, 1998，178，182-187