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研究领域

有机化学, 仿生催化,物理有机化学 金属卟啉仿生催化反应及其机理研究 具有新型催化活性的金属卟啉化合物合成

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Xiao Y, Luo W.-P., Zhang X.-Y., Guo C.-C.*, Liu Q, Jiang G.-F., Li, Q.-H. Aerobic oxidation of p-toluic acid to terephthalic acid over T(p-Cl)PPMnCl/Co(OAc)2 under moderate conditions. Catal. Lett., 2010, 134(1-2), 155-161. Liu Q, Gong Y.-Z., Gong C.-J., Li Q.-H., Guo C.-C.* A new one-pot synthesis of μ-oxo dimeric iron(III) porphyrins from meso-tetraarylporphyrins. J. Porphyrins Phthalocyanines, 2009, 13, 854-858. Guo, C.-C*, Liu, X.-Q., Liu, Q., Liu, Y., Chu, M.-F., Lin, W.-Y. First industrial-scale biomimetic oxidation of hydrocarbon with air over metalloporphyrins as cytochrome P-450 monooxygenase model and its mechanistic studies. J. Porphyrins Phthalocyanines, 2009, 13, 1250-1254. Hu B.-Y., Yuan Y.-J., Xiao J., Guo C.-C., Liu Q, Tan Z, Li Q-H. Rational oxidation of cyclohexane to cyclohexanol, cyclohexanone and adipic acid with air over metalloporphyrin and cobalt salt. J. Porphyrins Phthalocyanines, 2008, 12, 27-34. Jiang Q., Hu H.-Y., Guo C.-C., Liu Q., Song J.-X., Li Q.-H. Aerobic liquid-phase oxidation of p‑xylene over metalloporphyrins. J. Porphyrins and Phthalocyanines., 2007, 11(7): 524-530. Hu H.-Y., Jiang Q., Liu Q., Song J.-X., Lin W.-Y., Guo C.-C*. Catalysis of μ-oxo-bis[porphyriniron(III)] for toluene oxidation with molecular oxygen. J. Porphyrins and Phthalocyanines., 2006, 10(7): 948-952. Li Y.-F., Guo C.-C., Yan X.-H., Liu Q. Aerobic oxidative cleavage of C=C double bond of styrene catalyzed by simple manganese porphyrin. J. Porphyrins and Phthalocyanines., 2006, 10(7): 942-947. Guo C.-C.*, Liu Q., Wang X.-T., Hu H.-Y. Selective liquid phase oxidation of toluene with air. Appl. Catal. A: Gen., 2005, 282, 55-59. Guo C.-C.*, Peng Q.-J., Liu Q, Jiang GF. Selective oxidation of ethylbenzene with air catalyzed by simple μ-oxo dimeric metalloporphyrins under mild conditions in the absence of additives. J. Mol. Catal. A: Chem., 2003, 192(1-2): 295-302。 Guo C.-C*., Liu X.-Q., Liu Y., Liu Q., Chu M.-F., Zhang X.-B. Studies of simple μ-oxo-bisiron(III) -porphyrin as catalyst of cyclohexane oxidation with air in absence of cocatalysts or coreductants. J. Mol. Catal. A: Chem., 2003, 192, 289-294. Guo C.-C., Chu M.-F., Liu Q., Liu Y., Guo D.-C., Liu X.-Q. Effective catalysis of simple metalloporphyrins for cylohexane oxidation with air in the absence of additives and solvents. Appl. Catal. A: Gen., 2003, 246, 303-309. 梁学博, 胡伯羽, 袁永军, 刘强, 郭灿城. 金属卟啉催化空气氧化环己烷反应的工艺优化. 化工学报, 2007, 58(3): 794-800. 李勇飞, 严旭辉, 江国防, 刘强, 宋建新, 郭灿城. 金属卟啉催化的甲苯氧化及工艺优化. 中国化学工程学报(英文版), 2007, 15(3): 453-457.

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