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Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)]†
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-10-05 00:00:00 , DOI: 10.1039/c8dt03851a
Anders Reinholdt 1, 2, 3, 4 , Jesper Bendix 1, 2, 3, 4 , Anthony F. Hill 5, 6, 7, 8 , Richard A. Manzano 5, 6, 7, 8
Affiliation  

The reaction of [Ru(CAuCl)Cl2(PCy3)2] with [W([triple bond, length as m-dash]CSnnBu3)(CO)2(Tp*)] (obtained from [W([triple bond, length as m-dash]CBr)(CO)2(Tp*)], nBuLi and ClSnnBu3) affords the heterotetrametallic bis(carbido) complex [WRuAu2(μ-C)2Cl3(CO)2(PCy3)2(Tp*)] in which the two distinct μ-carbido ligands adopt linear and T-shaped geometry at carbon.

中文翻译:

不同碳氢化合物化学的融合:[WRuAu 2(μ-C)2 Cl 2(CO)2(PCy 32(Tp *)]

[Ru(CAuCl)Cl 2(PCy 32 ]与[W([三重键,长度为m-破折号]CSn n Bu 3)(CO)2(Tp *)](从[W([三重键,长度为m-破折号]CBr)(CO)2(Tp *)获得)的反应],n BuLi和ClSn n Bu 3)提供了异四金属双(碳基)配合物[WRuAu 2(μ-C)2 Cl 3(CO)2(PCy 32(Tp *)],其中两个截然不同的μ-碳原子配体在碳原子上呈线性和T形。
更新日期:2018-10-05
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