Metal Acetylacetonates as a Source of Metals for Aqueous Synthesis of Metal–Organic Frameworks,ACS Sustainable Chemistry & Engineering

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Metal Acetylacetonates as a Source of Metals for Aqueous Synthesis of Metal–Organic Frameworks
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2018-09-10 00:00:00 , DOI: 10.1021/acssuschemeng.8b03180
Ceren Avci-Camur ₁ , Javier Perez-Carvajal ₁ , Inhar Imaz ₁ , Daniel Maspoch _{1,

2}

Affiliation

Demand continues for environmentally sound, high-yielding processes for the large-scale production of metal–organic frameworks (MOFs). Here we describe the use of metal acetylacetonate complexes as an alternative source of metals for the aqueous synthesis of MOFs. We have synthesized several carboxylate-based Zr(IV)-(UiO-66-NH₂, Zr-fumarate, UiO-66-(OH)₂, UiO-66-COOH and UiO-66-(COOH)₂), Fe(III)-(MIL-88A) and Al(III)-(CAU-10) porous MOFs from their corresponding metal acetylacetonates in good yields (typically >85%) and, in some cases, at room temperature.

中文翻译：

乙酰丙酮金属盐作为金属有机框架水合成的金属来源

大规模生产金属有机框架（MOF）的环境无害，高产工艺的需求持续增长。在这里，我们描述了使用金属乙酰丙酮配合物作为MOFs水性合成的替代金属来源。我们合成了几种基于羧酸盐的Zr（IV）-（UiO-66-NH ₂，富马酸Zr-，UiO-66-（OH）₂，UiO-66-COOH和UiO-66-（COOH）₂），铁（III）-（MIL-88A）和Al（III）-（CAU-10）多孔MOF的收率较高（通常> 85％），并且在某些情况下还可以在室温下得到它们的相应金属乙酰丙酮化物。

更新日期：2018-09-10

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