Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst†,Chemical Communications

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Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-07-05 00:00:00 , DOI: 10.1039/c8cc04487b
Christian Schumacher _{1,

2,

3,

4} , Deborah E. Crawford _{5,

6,

7,

8} , Branimir Raguž _{4,

9,

10,

11} , Robert Glaum _{4,

9,

10,

11} , Stuart L. James _{5,

6,

7,

8} , Carsten Bolm _{1,

2,

3,

4} , José G. Hernández _{1,

2,

3,

4}

Affiliation

Mechanochemistry enabled the selective synthesis of the recherché orange polymorph of Wilkinson's catalyst [RhCl(PPh₃)₃]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me₂NH·BH₃ in a ball mill. The in situ-generated hydrogen (H₂) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.

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