Amine–Amine Electronic Coupling through a Dibenzo[a,e]pentalene Bridge,Organic Letters

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Amine–Amine Electronic Coupling through a Dibenzo[a,e]pentalene Bridge
Organic Letters ( IF 4.9 ) Pub Date : 2015-12-31 00:00:00 , DOI: 10.1021/acs.orglett.5b03408
Jun-Jian Shen ₁ , Jiang-Yang Shao ₁ , Xiaozhang Zhu ₁ , Yu-Wu Zhong ₁

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Three dibenzo[a,e]pentalene derivatives containing two redox-active amine substituents have been prepared. The degree of amine–amine electronic coupling through the dibenzo[a,e]pentalene bridge greatly depends on the substitution positions. Three monoamine compounds have been prepared for comparison studies. The experimental data and analysis were corroborated by time-dependent density functional theory results of mixed-valent compounds.

中文翻译：

通过二苯并[ a，e ]戊烯桥的胺-胺电子偶联

已经制备了三个含有两个氧化还原活性胺取代基的二苯并[ a，e ]戊烯衍生物。通过二苯并[ a，e ]戊烯桥的胺-胺电子偶联程度很大程度上取决于取代位置。已经准备了三种单胺化合物用于比较研究。混合价化合物随时间变化的密度泛函理论结果证实了实验数据和分析结果。

更新日期：2015-12-31

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