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N,N-bis(trimethylsilyl)methoxymethylamine as a convenient synthetic equivalent for +CH2NH2: N,N-bis(trimethylsilyl)aminomethylation of silyl sulphides and phosphites
Journal of the Chemical Society, Chemical Communications Pub Date : 1984 , DOI: 10.1039/c39840001055
Toshiaki Morimoto , Masahiro Aono , Minoru Sekiya

N-Silyl-protected primary aminomethyl sulphides and aminomethylphosphonates can be synthesised by the Lewis acid-catalysed reactions of silyl sulphides and silyl phosphites with N,N-bis(trimethylsilyl)methoxymethylamine.

中文翻译:

NN-双(三甲基甲硅烷基)甲氧基甲基胺,作为+ CH 2 NH 2的便捷合成当量:甲硅烷基硫化物和亚磷酸酯的NN-双(三甲基甲硅烷基)氨基甲基化

N-甲硅烷基保护的伯氨基甲基硫醚和氨基甲基膦酸酯可以通过路易斯酸催化的甲硅烷基硫醚和亚磷酸甲硅烷基酯与NN-双(三甲基甲硅烷基)甲氧基甲基胺的反应来合成。
更新日期:2017-01-31
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