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Water recovery from stripping gas overhead CO2 desorber through air cooling enhanced by transport membrane condensation
Separation and Purification Technology ( IF 8.1 ) Pub Date : 2019-01-23 , DOI: 10.1016/j.seppur.2019.01.058
Te Tu , Qiufang Cui , Feihong Liang , Liqiang Xu , Qingyao He , Shuiping Yan

At the CO2 regeneration stage in a CO2 chemical absorption process, the stripping gas (i.e., H2O(g)/CO2) leaving the CO2 desorber is cooled down to return the condensate into the desorber. Mostly the circulating cooling-water is used to provide this cooling duty. In this study, the air-cooling technology enhanced by transport membrane condensation was investigated with the aim of reducing the additional cooling-water duty of the chemical absorption process. A tubular hydrophilic ceramic membrane with the mean pore size of the inner separation layer of 4 nm and the length of 400 mm was used for water recovery from H2O(g)/CO2 using N2 as the sweeping gas. Results showed that the cooling performance of the N2-cooling ceramic membrane condenser is about 4–7 times higher than that of the N2-cooling stainless steel condenser with the same dimensions. For the water recovery from H2O(g)/CO2 using the N2-cooling ceramic membrane condenser, increasing the flow rate and pressure of inlet H2O(g)/CO2 can bring about the increase of the water transfer flux. The water transfer flux can increase with the H2O(g) molar fraction in H2O(g)/CO2 as well. Additionally, the increase of N2 flow rate in addition to the reduction of inlet N2 pressure can enhance the water transfer performance. Moreover, the temperatures of H2O(g)/CO2 and N2 have little impacts on the water transfer flux. Finally, an empirical correlation for predicting the water transfer flux as a function of the key operation variables was proposed for the N2-cooling ceramic membrane condenser. Most of the calculated water transfer flux data are in good agreement with the experimental results with an average absolute deviation of 12.5%.



中文翻译:

通过气态冷却从气提塔顶CO 2解吸器中回收水,该过程通过传输膜冷凝而增强

在CO 2化学吸收过程中的CO 2再生阶段,离开CO 2解吸器的汽提气(,H 2 O(g)/ CO 2)被冷却以使冷凝物返回解吸器。通常,循环冷却水用于提供这种冷却能力。在这项研究中,为了减少化学吸收过程中额外的冷却水负荷,研究了通过输送膜冷凝增强的空气冷却技术。使用内部分离层的平均孔径为4 nm,长度为400 mm的管状亲水性陶瓷膜从H 2 O(g)/ CO 2中使用N回收水2作为清扫气。结果表明,在相同尺寸下,N 2冷却陶瓷膜冷凝器的冷却性能大约是N 2冷却不锈钢冷凝器的4-7倍。对于使用N 2冷却陶瓷膜冷凝器从H 2 O(g)/ CO 2中回收水,增加进口H 2 O(g)/ CO 2的流量和压力可以增加水的转移。通量。在H 2 O(g)/ CO 2中,水的传递通量也可以随H 2 O(g)摩尔分数的增加而增加。另外,N 2的增加流速除了降低进口N 2压力外,还可以增强水的输送性能。而且,H 2 O(g)/ CO 2和N 2的温度对水传递通量的影响很小。最后,针对N 2冷却陶瓷膜冷凝器,提出了根据关键操作变量预测水流通量的经验相关性。计算出的大多数水转移通量数据与实验结果非常吻合,平均绝对偏差为12.5%。

更新日期:2019-01-23
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