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Hydrogen Evolution Catalyzed by Cobalt Diimine–Dioxime Complexes
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2015-05-05 00:00:00 , DOI: 10.1021/acs.accounts.5b00058 Nicolas Kaeffer 1 , Murielle Chavarot-Kerlidou 1 , Vincent Artero 1
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2015-05-05 00:00:00 , DOI: 10.1021/acs.accounts.5b00058 Nicolas Kaeffer 1 , Murielle Chavarot-Kerlidou 1 , Vincent Artero 1
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Mimicking photosynthesis and producing solar fuels is an appealing way to store the huge amount of renewable energy from the sun in a durable and sustainable way. Hydrogen production through water splitting has been set as a first-ranking target for artificial photosynthesis. Pursuing that goal requires the development of efficient and stable catalytic systems, only based on earth abundant elements, for the reduction of protons from water to molecular hydrogen. Cobalt complexes based on glyoxime ligands, called cobaloximes, emerged 10 years ago as a first generation of such catalysts. They are now widely utilized for the construction of photocatalytic systems for hydrogen evolution.
中文翻译：
钴二亚胺-二肟配合物催化析氢
模仿光合作用并生产太阳能燃料是以持久和可持续的方式储存大量来自太阳的可再生能源的一种有吸引力的方法。通过水分解制氢已被设定为人工光合作用的首要目标。实现这一目标需要开发仅基于地球丰富元素的高效稳定的催化系统，用于将质子从水还原为分子氢。基于乙二肟配体的钴络合物（称为钴肟）于 10 年前出现，是第一代此类催化剂。它们现在被广泛用于构建析氢光催化系统。
更新日期：2015-05-05
中文翻译：
钴二亚胺-二肟配合物催化析氢
模仿光合作用并生产太阳能燃料是以持久和可持续的方式储存大量来自太阳的可再生能源的一种有吸引力的方法。通过水分解制氢已被设定为人工光合作用的首要目标。实现这一目标需要开发仅基于地球丰富元素的高效稳定的催化系统，用于将质子从水还原为分子氢。基于乙二肟配体的钴络合物（称为钴肟）于 10 年前出现，是第一代此类催化剂。它们现在被广泛用于构建析氢光催化系统。
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