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Biobased Plasticizers from Carbohydrate-Derived 2,5-Bis(hydroxymethyl)furan
Industrial & Engineering Chemistry Research ( IF 3.8 ) Pub Date : 2019-01-10 , DOI: 10.1021/acs.iecr.8b05442
Bob A. Howell 1 , Simone T. Lazar 1
Affiliation  

As potential replacements for phthalate plasticizers, a series of esters of biobased 2,5-bis(hydroxymethyl)furan has been synthesized and fully characterized using spectroscopic and thermal methods. These materials are fully compatible with PVC and display a good plasticizing effect, comparable to that of common phthalate plasticizers. The presence of these materials does not diminish the thermal stability of the polymer, and they display a low migratory potential. These compounds would seem to represent attractive biobased alternatives to traditional phthalate esters for the plasticization of PVC.

中文翻译:

碳水化合物衍生的2,5-双(羟甲基)呋喃的生物基增塑剂

作为邻苯二甲酸酯类增塑剂的潜在替代品,已合成了一系列生物基2,5-双(羟甲基)呋喃酯,并使用光谱和热方法对其进行了全面表征。这些材料与PVC完全兼容,并具有与普通邻苯二甲酸酯增塑剂相当的增塑效果。这些材料的存在不会降低聚合物的热稳定性,并且它们显示出低的迁移潜力。这些化合物似乎代表了传统的邻苯二甲酸酯用于PVC增塑的有吸引力的生物基替代品。
更新日期:2019-01-11
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