Synthesis of Unsymmetrical Aromatic Azoxy Compounds by Silver‐Mediated Oxidative Coupling of Aromatic Amines with Nitrosoarenes,Advanced Synthesis & Catalysis

当前位置： X-MOL 学术 › Adv. Synth. Catal. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Synthesis of Unsymmetrical Aromatic Azoxy Compounds by Silver‐Mediated Oxidative Coupling of Aromatic Amines with Nitrosoarenes
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2019-01-29 , DOI: 10.1002/adsc.201801175
Weijie Ding ₁ , Shengshi Xu ₁ , Xiaochun Yu ₁ , Shun Wang ₁

Affiliation

A silver(I) oxide‐mediated synthesis of unsymmetrical aromatic azoxy compounds has been successfully achieved, wherein oxidative coupling reactions between aromatic amines and nitrosoarenes take place in ethanol under air. This reaction has very high economic value because silver(I) oxide is the only oxidant required and no other additive is needed. The resulted silver particles can be easily recovered, while the only other byproduct is water. This new procedure is compatible with various functional groups and proceeds under mild reaction conditions.

中文翻译：

银介导的芳胺与亚硝基芳烃的氧化偶合反应合成不对称芳族乙氧基化合物

已经成功实现了氧化银（I）介导的不对称芳族氮氧基化合物的合成，其中芳族胺与亚硝基芳烃之间的氧化偶联反应在空气中于乙醇中进行。该反应具有很高的经济价值，因为氧化银（I）是唯一需要的氧化剂，不需要其他添加剂。生成的银颗粒可以很容易地回收，而唯一的其他副产品是水。该新方法与各种官能团兼容，并在温和的反应条件下进行。

更新日期：2019-01-29

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南