Synthesis ( IF 2.2 ) Pub Date : 2018-12-12 , DOI: 10.1055/s-0037-1610328 Janakiram Vaitla 1 , Annette Bayer 1
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Abstract
As pioneered by Corey and Chaykovsky, sulfoxonium ylides have had widespread application in organic synthesis for more than a half century. In most of the reactions, sulfoxonium ylides were used to react with electrophiles. Under suitable reaction conditions these ylides can generate metal carbenoids and react with nucleophiles. By combining the typical reactivity of sulfoxonium ylides with transition-metal catalysis, a growing number of investigations have expanded their application in organic synthesis. This review provides an update on the preparation of sulfoxonium ylides and their applications in carbenoid transfer reactions.
1 Introduction
2 Preparation of Sulfoxonium Ylides
3 Investigation for Carbenoid Formation from Sulfoxonium Ylide
4 X–H (X = N, O, S, C) Functionalization Reactions
5 Polymerizaton of Carbenoids Generated from Sulfoxonium Ylides
6 Conclusion and Perspective
As pioneered by Corey and Chaykovsky, sulfoxonium ylides have had widespread application in organic synthesis for more than a half century. In most of the reactions, sulfoxonium ylides were used to react with electrophiles. Under suitable reaction conditions these ylides can generate metal carbenoids and react with nucleophiles. By combining the typical reactivity of sulfoxonium ylides with transition-metal catalysis, a growing number of investigations have expanded their application in organic synthesis. This review provides an update on the preparation of sulfoxonium ylides and their applications in carbenoid transfer reactions.
1 Introduction
2 Preparation of Sulfoxonium Ylides
3 Investigation for Carbenoid Formation from Sulfoxonium Ylide
4 X–H (X = N, O, S, C) Functionalization Reactions
5 Polymerizaton of Carbenoids Generated from Sulfoxonium Ylides
6 Conclusion and Perspective
中文翻译：
有机合成中由Y硫鎓叶立德衍生的金属类化合物
摘要
正如Corey和Chaykovsky所率先提出的，亚磺酰ides已经在有机合成中广泛应用了半个多世纪。在大多数反应中，使用亚硫酸sulf与亲电子试剂反应。在合适的反应条件下，这些叶立德可以生成金属类胡萝卜素并与亲核试剂反应。通过将典型的of氧化物的反应性与过渡金属催化相结合，越来越多的研究扩展了它们在有机合成中的应用。这篇综述提供了关于亚砜基鎓盐的制备及其在类胡萝卜素转移反应中的应用的最新信息。
1个 介绍
2个 制备亚硫酸ulf盐
3 硫代on盐形成类胡萝卜素的研究
4 X–H（X = N，O，S，C）官能化反应
5 Y鎓叶立德产生的类胡萝卜素的聚合
6 结论与展望
正如Corey和Chaykovsky所率先提出的，亚磺酰ides已经在有机合成中广泛应用了半个多世纪。在大多数反应中，使用亚硫酸sulf与亲电子试剂反应。在合适的反应条件下，这些叶立德可以生成金属类胡萝卜素并与亲核试剂反应。通过将典型的of氧化物的反应性与过渡金属催化相结合，越来越多的研究扩展了它们在有机合成中的应用。这篇综述提供了关于亚砜基鎓盐的制备及其在类胡萝卜素转移反应中的应用的最新信息。
1个 介绍
2个 制备亚硫酸ulf盐
3 硫代on盐形成类胡萝卜素的研究
4 X–H（X = N，O，S，C）官能化反应
5 Y鎓叶立德产生的类胡萝卜素的聚合
6 结论与展望
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