Diazo Compounds: Versatile Synthons for the Synthesis of Nitrogen Heterocycles via Transition Metal‐Catalyzed Cascade C–H Activation/Carbene Insertion/Annulation Reactions,Advanced Synthesis & Catalysis

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Diazo Compounds: Versatile Synthons for the Synthesis of Nitrogen Heterocycles via Transition Metal‐Catalyzed Cascade C–H Activation/Carbene Insertion/Annulation Reactions
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-11-27 , DOI: 10.1002/adsc.201800960
Yunyu Xiang ₁ , Cong Wang ₁ , Qiuping Ding ₁ , Yiyuan Peng ₁

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This review covers some unique diazo compounds, the coupling partners to access various versatile functionalized nitrogen heterocycles, such as indoles, indolines, isoquinolines, isoquinolones, and so on. Different transition metals (such as Rh, Pd, Ru, Ir, Cu, and Co) are involved in these transformations, which involve consecutive processes: transition metal‐catalyzed cascade C–H activation/carbene insertion/intramolecular annulation.

中文翻译：

重氮化合物：通过过渡金属催化的级联C–H活化/碳原子插入/环化反应合成氮杂环的多功能合成子

这篇综述涵盖了一些独特的重氮化合物，偶联伙伴，以使用各种通用的功能化氮杂环，例如吲哚，二氢吲哚，异喹啉，异喹啉等。这些转变涉及不同的过渡金属（例如Rh，Pd，Ru，Ir，Cu和Co），这些过程涉及连续的过程：过渡金属催化的级联C–H活化/卡宾插入/分子内环化。

更新日期：2018-11-27

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