Palladium-Catalyzed Asymmetric C–H Arylation for the Synthesis of Planar Chiral Benzothiophene-Fused Ferrocenes,ACS Catalysis

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Palladium-Catalyzed Asymmetric C–H Arylation for the Synthesis of Planar Chiral Benzothiophene-Fused Ferrocenes
ACS Catalysis ( IF 11.3 ) Pub Date : 2018-11-12 00:00:00 , DOI: 10.1021/acscatal.8b03912
Bing-Bin Xu ₁ , Jie Ye ₁ , Yu Yuan ₁ , Wei-Liang Duan ₁

Affiliation

An intramolecular enantioselective C–H arylation of ferrocenyl aryl sulfides was performed with a palladium catalyst. Planar chiral thiophene compounds with a ferrocene skeleton were constructed in good enantioselectivities (up to 99% ee) and high yields, and the utility of the obtained chiral sulfides as ligands in catalytic reactions has been demonstrated.

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