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Synergistic Extraction of Hydroquinone from Aqueous Solution with Solvent Mixture of 2-Pentanone and n-Pentanol: Liquid–Liquid Equilibria and Data Correlation
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2018-11-08 , DOI: 10.1021/acs.jced.8b00660 Chao Guo 1 , Yangtong Tan 1 , Yu Qian 1 , Siyu Yang 1
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2018-11-08 , DOI: 10.1021/acs.jced.8b00660 Chao Guo 1 , Yangtong Tan 1 , Yu Qian 1 , Siyu Yang 1
Affiliation
The synergistic effect for a solvent mixture of 2-pentanone and n-pentanol to extract hydroquinone from aqueous solution was investigated. Liquid–liquid equilibria data for the quaternary (2-pentanone + n-pentanol + hydroquinone + water) system were measured under atmospheric pressure at 298.2 K, using various compositions of solvent mixture. The tie-line length was calculated to estimate the size of the immiscibility zone. The distribution coefficient and separation factor were calculated to evaluate the extraction efficiencies. The experimental data were correlated with NRTL and UNIQUAC models, and the corresponding binary interaction parameters were obtained.
中文翻译:
2-戊酮和正戊醇混合溶剂从水溶液中协同萃取对苯二酚:液-液平衡和数据关联
研究了2-戊酮和正戊醇的混合溶剂从水溶液中提取对苯二酚的协同作用。季铵盐(2-戊酮+正戊醇+对苯二酚+水)体系的液-液平衡数据是在大气压下于298.2 K下使用各种溶剂混合物组成进行测量的。计算联络线长度以估计不混溶区的大小。计算分配系数和分离系数以评估提取效率。将实验数据与NRTL和UNIQUAC模型进行关联,得到相应的二元相互作用参数。
更新日期:2018-11-09
中文翻译:
2-戊酮和正戊醇混合溶剂从水溶液中协同萃取对苯二酚:液-液平衡和数据关联
研究了2-戊酮和正戊醇的混合溶剂从水溶液中提取对苯二酚的协同作用。季铵盐(2-戊酮+正戊醇+对苯二酚+水)体系的液-液平衡数据是在大气压下于298.2 K下使用各种溶剂混合物组成进行测量的。计算联络线长度以估计不混溶区的大小。计算分配系数和分离系数以评估提取效率。将实验数据与NRTL和UNIQUAC模型进行关联,得到相应的二元相互作用参数。