Palladium-Catalyzed Carbon Isotope Exchange on Aliphatic and Benzoic Acid Chlorides,Journal of the American Chemical Society

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Palladium-Catalyzed Carbon Isotope Exchange on Aliphatic and Benzoic Acid Chlorides
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2018-11-01 , DOI: 10.1021/jacs.8b09808
Donald R. Gauthier ₁ , Nelo R. Rivera ₁ , Haifeng Yang ₁ , Danielle M. Schultz ₁ , C. Scott Shultz ₁

Affiliation

An operationally simple protocol for a palladium-catalyzed 13CO and 14CO exchange with activated aliphatic and benzoic carbonyls is presented. Several 13C and 14C building blocks, natural product derivatives, and pharmaceuticals have been prepared to showcase the method for late-stage carbon isotope incorporation and its functional group compatibility.

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