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Hydrophobic Deep Eutectic Solvents Incorporating Trioctylphosphine Oxide: Advanced Liquid Extractants
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2018-10-26 00:00:00 , DOI: 10.1021/acssuschemeng.8b04843 Mark Gilmore 1 , Éadaoin N. McCourt 1 , Francis Connolly 1 , Peter Nockemann 1 , Małgorzata Swadźba-Kwaśny 1 , John D. Holbrey 1
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2018-10-26 00:00:00 , DOI: 10.1021/acssuschemeng.8b04843 Mark Gilmore 1 , Éadaoin N. McCourt 1 , Francis Connolly 1 , Peter Nockemann 1 , Małgorzata Swadźba-Kwaśny 1 , John D. Holbrey 1
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A low viscosity, hydrophobic eutectic solvent based on trioctylphosphine oxide (TOPO) has been developed and characterized, and its use as an extractant demonstrated for liquid–liquid separation of uranyl nitrate from aqueous acid. This strategy of liquefying the active extracting agent as a eutectic liquid produced liquids that contain an intrinsically high concentration of TOPO (ca. 80 wt %, 1.875 mol L–1 at χTOPO = 0.50) and renders the use of an organic (hydrocarbon) diluent redundant.
中文翻译：
含三辛基膦氧化物的疏水性深共晶溶剂：先进的液体萃取剂
一种基于三辛基氧化膦（TOPO）的低粘度疏水共晶溶剂已被开发和表征，其作为萃取剂的用途已证明可用于从含水酸液中进行液-液分离硝酸铀酰。这种将活性萃取剂液化为低共熔液体的策略产生的液体本质上含有高浓度的TOPO（在x TOPO = 0.50时约为80 wt％，1.875 mol L –1），并使用了有机物（烃）稀释剂多余。
更新日期：2018-10-26
中文翻译：
含三辛基膦氧化物的疏水性深共晶溶剂：先进的液体萃取剂
一种基于三辛基氧化膦（TOPO）的低粘度疏水共晶溶剂已被开发和表征，其作为萃取剂的用途已证明可用于从含水酸液中进行液-液分离硝酸铀酰。这种将活性萃取剂液化为低共熔液体的策略产生的液体本质上含有高浓度的TOPO（在x TOPO = 0.50时约为80 wt％，1.875 mol L –1），并使用了有机物（烃）稀释剂多余。
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