Solvent‐free protocols for Miyaura borylation and the one‐pot, two‐step homocoupling of aryl halides are reported for the first time. Bis(dibenzylideneacetone)palladium(0) [Pd(dba)₂] is an optimal source of palladium for Miyaura borylation, while for one‐pot two‐step homocoupling palladium(II) acetate [Pd(OAc)₂] gives highest yields. Aryl bromides are coupled most efficiently using the DPEphos ligand. Chlorides are coupled using XPhos. The developed protocols are robust, versatile and easily reproducible on a large scale.

中文翻译：

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无溶剂条件下的芳浦硼化和芳基氯化物和溴化物的一锅两步均偶联

首次报道了宫浦硼化反应的无溶剂方案和芳基卤化物的一锅，两步均偶联。双（二亚苄基丙酮）钯（0）​​[Pd（dba）₂ ]是用于宫浦硼酸化的最佳钯来源，而对于一锅两步均偶联的乙酸钯（II）[Pd（OAc）₂ ]则可提供最高的收率。使用DPEphos配体可以最有效地偶联芳基溴化物。氯化物使用XPhos偶联。所开发的协议功能强大，用途广泛且易于大规模复制。