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Efficient Visible-Light Photocatalysis of 2D-MXene Nanohybrids with Gd3+- and Sn4+-Codoped Bismuth Ferrite
ACS Omega ( IF 3.7 ) Pub Date : 2018-10-22 00:00:00 , DOI: 10.1021/acsomega.8b01951
Ayesha Tariq 1 , S Irfan Ali 2, 2 , Deji Akinwande 3 , Syed Rizwan 1
Affiliation  

Nowadays, photocatalysis has gained tremendous interest owing to the fact that it can overcome water crisis as well as the environmental issues by utilizing a major source of solar energy. The nanohybrid structures of Gd3+- and Sn4+-doped bismuth ferrite (Bi1–xGdxFe1–ySny; BGFSO) with two-dimensional (2D) MXene sheets are synthesized by the coprecipitation method. The 2D sheets have a large surface area, incorporation of which into Bi1–xGdxFe1–ySny (BGFSO) nanoparticles provides a path for electrons to flow, which results in large recombination time and thus enhances dye degradation. The Bi0.90Gd0.10Fe0.80Sn0.20O3/MXene (BGFO-20Sn/MXene) nanohybrid shows 100% degradation of Congo dye from the catalytic solution in 120 min, which is highly efficient for industrial application.

中文翻译:

具有 Gd3+- 和 Sn4+- 共掺杂铁酸铋的 2D-MXene 纳米杂化物的高效可见光光催化

如今,光催化因其可以利用太阳能的主要来源来克服水危机和环境问题而引起了极大的兴趣。通过共沉淀法合成了具有二维 (2D) MXene 片的 Gd 3+和 Sn 4+掺杂铋铁氧体 (Bi 1– x Gd x Fe 1– y Sn y ; BGFSO) 纳米杂化结构。二维片材具有较大的表面积,将其掺入 Bi 1– x Gd x Fe 1– y Sn y (BGFSO) 纳米颗粒中可以为电子流动提供路径,从而导致较长的复合时间,从而增强染料降解。Bi 0.90 Gd 0.10 Fe 0.80 Sn 0.20 O 3 /MXene (BGFO-20Sn/MXene) 纳米杂化物表现出在 120 分钟内从催化溶液中 100% 降解刚果染料,这对于工业应用来说是非常高效的。
更新日期:2018-10-22
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