Revisiting Sodium Hypochlorite Pentahydrate (NaOCl·5H2O) for the Oxidation of Alcohols in Acetonitrile without Nitroxyl Radicals,Synlett

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Revisiting Sodium Hypochlorite Pentahydrate (NaOCl·5H2O) for the Oxidation of Alcohols in Acetonitrile without Nitroxyl Radicals
Synlett ( IF 1.7 ) Pub Date : 2018-10-17 , DOI: 10.1055/s-0037-1609629
Tsunehisa Hirashita ₁ , Yuto Sugihara , Shota Ishikawa , Yohei Naito , Yuta Matsukawa , Shuki Araki

Affiliation

Sodium hypochlorite pentahydrate (NaOCl·5H2O) is capable of oxidizing alcohols in acetonitrile at 20 °C without the use of catalysts. The oxidation is selective to allylic, benzylic, and secondary alcohols. Aliphatic primary alcohols are not oxidized.

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