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Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
Chemical Reviews ( IF 51.4 ) Pub Date : 2016-02-17 00:00:00 , DOI: 10.1021/acs.chemrev.5b00462 Minhua Shao 1 , Qiaowan Chang 1 , Jean-Pol Dodelet 2 , Regis Chenitz 2
Chemical Reviews ( IF 51.4 ) Pub Date : 2016-02-17 00:00:00 , DOI: 10.1021/acs.chemrev.5b00462 Minhua Shao 1 , Qiaowan Chang 1 , Jean-Pol Dodelet 2 , Regis Chenitz 2
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The recent advances in electrocatalysis for oxygen reduction reaction (ORR) for proton exchange membrane fuel cells (PEMFCs) are thoroughly reviewed. This comprehensive Review focuses on the low- and non-platinum electrocatalysts including advanced platinum alloys, core–shell structures, palladium-based catalysts, metal oxides and chalcogenides, carbon-based non-noble metal catalysts, and metal-free catalysts. The recent development of ORR electrocatalysts with novel structures and compositions is highlighted. The understandings of the correlation between the activity and the shape, size, composition, and synthesis method are summarized. For the carbon-based materials, their performance and stability in fuel cells and comparisons with those of platinum are documented. The research directions as well as perspectives on the further development of more active and less expensive electrocatalysts are provided.
中文翻译：
氧还原反应用电催化剂的最新进展
对质子交换膜燃料电池（PEMFC）的氧还原反应（ORR）电催化的最新进展进行了全面回顾。这份全面的综述重点关注低铂和非铂电催化剂，包括高级铂合金，核-壳结构，钯基催化剂，金属氧化物和硫族化物，碳基非贵金属催化剂和无金属催化剂。着重介绍了具有新颖结构和组成的ORR电催化剂的最新发展。总结了对活性与形状，大小，组成和合成方法之间的相关性的理解。对于碳基材料，已记录了它们在燃料电池中的性能和稳定性以及与铂的比较。
更新日期：2016-02-17
中文翻译：
氧还原反应用电催化剂的最新进展
对质子交换膜燃料电池（PEMFC）的氧还原反应（ORR）电催化的最新进展进行了全面回顾。这份全面的综述重点关注低铂和非铂电催化剂，包括高级铂合金，核-壳结构，钯基催化剂，金属氧化物和硫族化物，碳基非贵金属催化剂和无金属催化剂。着重介绍了具有新颖结构和组成的ORR电催化剂的最新发展。总结了对活性与形状，大小，组成和合成方法之间的相关性的理解。对于碳基材料，已记录了它们在燃料电池中的性能和稳定性以及与铂的比较。
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