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Hierarchical bi-continuous Pt decorated nanoporous Au-Sn alloy on carbon fiber paper for ascorbic acid, dopamine and uric acid simultaneous sensing
Biosensors and Bioelectronics ( IF 10.7 ) Pub Date : 2018-10-13 , DOI: 10.1016/j.bios.2018.10.012
Han Yang , Jie Zhao , Meijia Qiu , Peng Sun , Dongxue Han , Li Niu , Guofeng Cui

In this work, Pt nanoparticles modified nanoporous AuSn([email protected]) alloy on Ni buffered flexible carbon fiber paper (CFP) is fabricated by a simple replacement reaction in which NP-AuSn is fabricated by controllable dealloy of electrodeposited Au-Sn alloy films. The as prepared [email protected]/Ni/CFP possesses hierarchical pore structure, high specific surface area and excellent catalytic activity. Due to the bi-functions of both the large surface area of nanoporous metal and macroporous of carbon fiber paper facilitating mass transfer, the [email protected]/Ni/CFP shows high sensitivity of detecting ascorbic acid (AA), dopamine (DA) and uric acid (UA), with sensitivities of 0.14 μA μM−1 cm−2, 15.23 μA μM−1 cm−2, 0.28 μA μM−1 cm−2 under the concentration ranging from 200 to 2000 μM, 1–10 μM, and 25–800 μM for AA, DA and UA, respectively. Further, the [email protected]/Ni/CFP possesses long-term stability of sensing AA, DA and UA and presents great anti-interference towards a variety of common compounds in body fluid. All of these results manifest the [email protected]/Ni/CFP can be a promising candidate for the application of the electrochemical sensor for simultaneous detection of AA, DA and UA.



中文翻译:

碳纤维纸上分层双连续Pt修饰的纳米多孔Au-Sn合金用于抗坏血酸,多巴胺和尿酸的同时感测

在这项工作中,通过简单的置换反应在镍缓冲的柔性碳纤维纸(CFP)上制备了Pt纳米粒子改性的纳米多孔AuSn([受电子邮件保护])合金,其中通过可控的电沉积Au-Sn合金来制备NP-AuSn。电影。所制备的[受电子邮件保护的] / Ni / CFP具有分级的孔结构,高比表面积和出色的催化活性。由于纳米孔金属的大表面积和碳纤维纸的大孔都具有双重功能,从而促进了质量传递,因此[电子邮件保护] / Ni / CFP显示出检测抗坏血酸(AA),多巴胺(DA)和多巴胺的高灵敏度。尿酸(UA),0.14μAμM灵敏度-1厘米-2,15.23μAμM -1厘米-2,0.28μAμM -1厘米-2范围从200到2000微米,1-10微米,25-800微米,用于分别AA,DA和UA,该浓度下。此外,[电子邮件保护] / Ni / CFP具有检测AA,DA和UA的长期稳定性,并且对体液中的多种常见化合物具有极大的抗干扰性。所有这些结果表明,[电子邮件保护] / Ni / CFP可能是用于同时检测AA,DA和UA的电化学传感器应用的有前途的候选者。

更新日期:2018-10-13
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