超氧化物离子：产生及其化学意义,Chemical Reviews

当前位置： X-MOL 学术 › Chem. Rev. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

超氧化物离子：产生及其化学意义
Chemical Reviews ( IF 51.4 ) Pub Date : 2016-02-15 00:00:00 , DOI: 10.1021/acs.chemrev.5b00407
Maan Hayyan , Mohd Ali Hashim , Inas M. AlNashef ₁

Affiliation

作为涉及多种化学和生物系统的自由基，超氧离子（O ₂^•–）具有重要意义。但是，O ₂^•–的化学知识相当匮乏。此外，在20世纪下半叶，对O ₂^•进行了大量研究。因此，当前技术和仪器的进步必将为O ₂^•反应的机理和产物提供更好的见解，从而带来新的发现。这篇综述着重介绍了关于O ₂^•的最新研究，以使研究人员能够冒险进行未来的研究。它包括O ₂的主要特征^•–其次是生成方法。对O ₂^•的反应类型进行了综述，并重点介绍了其潜在的应用，包括破坏有害化学物质，合成有机化合物以及许多其他应用。还讨论了O ₂^•–环境化学。对O ₂^•–的检测方法进行了分类和阐述。特别注意使用离子液体作为O ₂^•的介质的可行性，以解决生成和应用的最新进展。综述了电极对O ₂^•电化学生成的影响。最后，总结了一些言论和未来展望。

"点击查看英文标题和摘要"

Superoxide Ion: Generation and Chemical Implications

Superoxide ion (O₂^•–) is of great significance as a radical species implicated in diverse chemical and biological systems. However, the chemistry knowledge of O₂^•– is rather scarce. In addition, numerous studies on O₂^•– were conducted within the latter half of the 20th century. Therefore, the current advancement in technology and instrumentation will certainly provide better insights into mechanisms and products of O₂^•– reactions and thus will result in new findings. This review emphasizes the state-of-the-art research on O₂^•– so as to enable researchers to venture into future research. It comprises the main characteristics of O₂^•– followed by generation methods. The reaction types of O₂^•– are reviewed, and its potential applications including the destruction of hazardous chemicals, synthesis of organic compounds, and many other applications are highlighted. The O₂^•– environmental chemistry is also discussed. The detection methods of O₂^•– are categorized and elaborated. Special attention is given to the feasibility of using ionic liquids as media for O₂^•–, addressing the latest progress of generation and applications. The effect of electrodes on the O₂^•– electrochemical generation is reviewed. Finally, some remarks and future perspectives are concluded.

更新日期：2016-02-15

点击分享查看原文

点击收藏

公开下载

阅读更多本刊新发论文本刊介绍/投稿指南