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Copper(II) Triflate‐Catalyzed Aerobic Oxidative C?H Functionalization of Glycine Derivatives with Olefins and Organoboranes
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2016-02-15 , DOI: 10.1002/adsc.201501015
Zhiyu Xie , Jiong Jia , Xigong Liu , Lei Liu

An economical, and practical copper(II) triflate‐catalyzed aerobic oxidative CH functionalization of glycine derivatives with olefins and organoboranes has been established. The mild reaction has an excellent functional group tolerance, and exhibits a broad scope with respect to both glycine derivatives and the two types of nucleophilic components, allowing for the facile synthesis of diverse substituted quinolines and glycine derivatives bearing various patterns of functionalities in the α‐position.

中文翻译:

三氟甲磺酸铜(II)催化的好氧氧化C 甘氨酸衍生物与烯烃和有机果糖的H功能化

建立了经济实用的三氟甲磺酸铜(II)催化甘氨酸衍生物与烯烃和有机硼烷的好氧氧化CH功能化。温和的反应具有优异的官能团耐受性,并且在甘氨酸衍生物和两种类型的亲核组分方面均显示出广阔的范围,从而可以轻松合成各种取代的喹啉和甘氨酸衍生物,这些衍生物在α-中具有各种功能模式位置。
更新日期:2016-02-15
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