P,P-Dimethylformylphosphine: The Phosphorus Analogue of DMF,Journal of the American Chemical Society

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P,P-Dimethylformylphosphine: The Phosphorus Analogue of DMF
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2018-10-01 , DOI: 10.1021/jacs.8b09266
Kevin M. Szkop ₁ , Andrew R. Jupp ₁ , Douglas W. Stephan ₁

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The neutral PCO derivative Ph3GePCO undergoes addition of borohydride to generate the anion [Ph3GePC(H)OBPh3]-. A subsequent deprotection strategy provides access to the monomethyl and dimethylformyl phosphines, Ph3GeP(Me)C(H)O and Me2PC(H)O, respectively. The latter species which is the phosphorus analogue of DMF, was characterized and shown to complex via phosphorus to Ru. A computational study also highlights the similarities and differences between the P- and N-containing molecules.

中文翻译：

P,P-二甲基甲酰基膦：DMF 的磷类似物

中性 PCO 衍生物 Ph3GePCO 加入硼氢化物后生成阴离子 [Ph3GePC(H)OBPh3]-。随后的脱保护策略分别提供了对单甲基和二甲基甲酰基膦、Ph3GeP(Me)C(H)O 和 Me2PC(H)O 的访问。后一种物质是 DMF 的磷类似物，被表征并显示通过磷与 Ru 络合。一项计算研究还强调了含 P 和 N 分子之间的异同。

更新日期：2018-10-01

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