Advances in Synthetic Applications of Hypervalent Iodine Compounds,Chemical Reviews

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Advances in Synthetic Applications of Hypervalent Iodine Compounds
Chemical Reviews ( IF 51.4 ) Pub Date : 2016-02-10 00:00:00 , DOI: 10.1021/acs.chemrev.5b00547
Akira Yoshimura ₁ , Viktor V. Zhdankin ₁

Affiliation

The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed with emphasis on their synthetic application. Compounds of iodine possess reactivity similar to that of transition metals, but have the advantage of environmental sustainability and efficient utilization of natural resources. These compounds are widely used in organic synthesis as selective oxidants and environmentally friendly reagents. Synthetic uses of hypervalent iodine reagents in halogenation reactions, various oxidations, rearrangements, aminations, C–C bond-forming reactions, and transition metal-catalyzed reactions are summarized and discussed. Recent discovery of hypervalent catalytic systems and recyclable reagents, and the development of new enantioselective reactions using chiral hypervalent iodine compounds represent a particularly important achievement in the field of hypervalent iodine chemistry. One of the goals of this Review is to attract the attention of the scientific community as to the benefits of using hypervalent iodine compounds as an environmentally sustainable alternative to heavy metals.

中文翻译：

高价碘化合物的合成应用进展

对高价碘化合物的制备，结构和化学进行了综述，重点是其合成应用。碘化合物具有与过渡金属相似的反应性，但具有环境可持续性和有效利用自然资源的优势。这些化合物广泛用作有机合成中的选择性氧化剂和环保试剂。总结和讨论了高价碘试剂在卤化反应，各种氧化，重排，胺化，CC键形成反应和过渡金属催化反应中的合成应用。高价催化系统和可循环利用试剂的最新发现，使用手性高价碘化合物开发新的对映选择性反应代表了高价碘化学领域的一项重要成就。该评论的目标之一是引起科学界的关注，即使用高价碘化合物作为重金属在环境上可持续的替代品的好处。

更新日期：2016-02-10

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