Markovnikov Hydrosilylation of Alkenes: How an Oddity Becomes the Goal,ACS Catalysis

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Markovnikov Hydrosilylation of Alkenes: How an Oddity Becomes the Goal
ACS Catalysis ( IF 11.3 ) Pub Date : 2018-09-13 00:00:00 , DOI: 10.1021/acscatal.8b03104
Maciej Zaranek ₁ , Piotr Pawluc ₁

Affiliation

Over the years, hydrosilylation of terminal alkenes has emerged as one of the most prominent applications of homogeneous catalysis. While most of the relevant reports concern β-selective hydrosilylation, yielding linear products which are of industrial importance, the opposite selectivity is also gaining increasing interest and sets the scene for the next challenges. Markovnikov hydrosilylation of alkenes, especially in its asymmetric variant, has become the aim of development of new catalytic systems successfully implementing base-metal complexes—one of the most prominent trends in contemporary catalysis. In this Perspective, we present the current state of this topic and the way it has been achieved, with special emphasis put on the issues still unresolved and prospective directions of development based on the trends present in the literature, but without unnecessary attention to some details of only historical significance.

中文翻译：

烯烃的马尔科夫尼科夫氢化硅烷化：奇数如何成为目标

多年来，末端烯烃的氢化硅烷化已成为均相催化的最突出应用之一。尽管大多数相关报道都涉及β-选择性氢化硅烷化，产生具有工业重要性的线性产品，但相反的选择性也引起了越来越多的关注，并为下一个挑战奠定了基础。马尔可夫尼可夫烯烃的氢化硅烷化，特别是不对称形式的烯烃，已经成为开发成功实施贱金属配合物的新型催化体系的目标，这是当代催化最重要的趋势之一。在此观点中，我们介绍了该主题的当前状态及其实现方式，并特别强调了仍未解决的问题以及根据文献中的趋势得出的未来发展方向，

更新日期：2018-09-13

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