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Recent Advances of Cellulose‐Based Materials and Their Promising Application in Sodium‐Ion Batteries and Capacitors
Small ( IF 13.0 ) Pub Date : 2018-09-09 , DOI: 10.1002/smll.201802444
Tianyun Zhang 1, 2, 3 , Liang Yang 2 , Xingbin Yan 3 , Xin Ding 1
Affiliation  

Cellulose as the most abundant natural biopolymer on earth has shown promising potential because of its excellent physical, mechanical, and biocompatible properties, which are very important for sustainable energy storage systems (ESSs). In this review, a comprehensive summary of the applications involving all kinds and forms of cellulose in the advanced Na‐related ESSs, including sodium ion batteries (SIBs) and sodium ion capacitors (SICs), is presented. For cellulose, the impact of various structures and surface chemical properties on the electrochemical performance is focused on. In particular, the latest developments in cellulose‐based binders and separators are highlighted. In addition, an in‐depth understanding of the structure and performance of electrode materials and the storage mechanism of a hard carbon anode derived from cellulose for SIBs is provided. Further, the manufacturing of full‐cellulose‐based SICs assembled by all parts of devices including hard carbon anodes, active carbon cathodes, binders, and separator based on cellulose or cellulose derivatives is reviewed. Finally, the prospects of cellulose‐based energy storage systems on several issues that need further exploration are presented.

中文翻译:

纤维素基材料的最新进展及其在钠离子电池和电容器中的应用前景

纤维素作为地球上最丰富的天然生物聚合物,因其优异的物理,机械和生物相容性而具有广阔的发展前景,这对可持续能源存储系统(ESS)至关重要。在本综述中,将对涉及钠的高级ESS中所有种类和形式的纤维素的应用进行全面总结,包括钠离子电池(SIB)和钠离子电容器(SIC)。对于纤维素,关注各种结构和表面化学性质对电化学性能的影响。特别要强调的是纤维素基粘合剂和隔离剂的最新发展。此外,提供了对电极材料的结构和性能以及源自纤维素的硬碳阳极用于SIB的存储机理的深入了解。此外,对由设备的所有部件组装而成的全纤维素SIC的制造进行了审查,包括硬碳阳极,活性碳阴极,粘合剂和基于纤维素或纤维素衍生物的隔膜。最后,介绍了纤维素储能系统在一些需要进一步探索的问题上的前景。
更新日期:2018-09-09
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