Repurposing Biocatalysts to Control Radical Polymerizations,ACS Macro Letters

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Repurposing Biocatalysts to Control Radical Polymerizations
ACS Macro Letters ( IF 5.1 ) Pub Date : 2018-09-04 00:00:00 , DOI: 10.1021/acsmacrolett.8b00561
Kyle J Rodriguez ₁ , Bernadetta Gajewska ₁ , Jonas Pollard ₁ , Michela M Pellizzoni ₁ , Csaba Fodor ₁ , Nico Bruns ₁

Affiliation

Reversible-deactivation radical polymerizations (controlled radical polymerizations) have revolutionized and revitalized the field of polymer synthesis. While enzymes and other biologically derived catalysts have long been known to initiate free radical polymerizations, the ability of peroxidases, hemoglobin, laccases, enzyme-mimetics, chlorophylls, heme, red blood cells, bacteria, and other biocatalysts to control or initiate reversible-deactivation radical polymerizations has only been described recently. Here, the scope of biocatalytic atom transfer radical polymerizations (bioATRP), enzyme-initiated reversible addition–fragmentation chain transfer radical polymerizations (bioRAFT), biocatalytic organometallic-mediated radical polymerizations (bioOMRP), and biocatalytic reversible complexation mediated polymerizations (bioRCMP) is critically reviewed, and the potential of these reactions for the environmentally friendly synthesis of precision polymers, for the preparation of functional nanostructures, for the modification of surfaces, and for biosensing is discussed.

中文翻译：

重新利用生物催化剂来控制自由基聚合

可逆失活自由基聚合（受控自由基聚合）已经彻底改变并振兴了聚合物合成领域。虽然早就知道酶和其他生物衍生催化剂会引发自由基聚合，但过氧化物酶、血红蛋白、漆酶、酶模拟物、叶绿素、血红素、红细胞、细菌和其他生物催化剂控制或引发可逆失活的能力自由基聚合最近才被描述。在这里，生物催化原子转移自由基聚合（bioATRP）、酶引发的可逆加成-断裂链转移自由基聚合（bioRAFT）、生物催化有机金属介导自由基聚合（bioOMRP）的范围，

更新日期：2018-09-04

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