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Densities and Viscosities for the Ternary System of exo-Tetrahydrodicyclopentadiene (1) + Methylcyclohexane (2) + Cyclopropanemethanol (3) and Its Binaries at T = 293.15 to 333.15 K
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2018-08-16 , DOI: 10.1021/acs.jced.8b00409
Shenda Jin 1 , Xi Wu 1 , Yitong Dai 1 , Yongsheng Guo 1 , Wenjun Fang 1
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2018-08-16 , DOI: 10.1021/acs.jced.8b00409
Shenda Jin 1 , Xi Wu 1 , Yitong Dai 1 , Yongsheng Guo 1 , Wenjun Fang 1
Affiliation
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Measurements on densities (ρ) and viscosities (η) at nine temperatures from 293.15 to 333.15 K and the pressure p = 0.1 MPa for the ternary system of exo-tetrahydrodicyclopentadiene (1) + methylcyclohexane (2) + cyclopropanemethanol (3) and the corresponding binary systems have been carried out over the whole composition range. The excess molar volumes (VmE) and viscosity deviations (Δη) of the ternary system have been calculated and fitted to the Nagata–Tamura equation, while those of the binary systems have been calculated and fitted to the Redlich–Kister equation. The excess properties and deviation phenomena were discussed from the viewpoints of molecular interactions and structural effects. These fundamental results can be used to learn the nature of mixed hydrocarbon fuels.
中文翻译:
外-四氢二环戊二烯(1)+甲基环己烷(2)+环丙烷甲醇(3)及其二元三元体系的三元密度和粘度在T = 293.15至333.15 K
外-四氢二环戊二烯(1)+甲基环己烷(2)+环丙烷甲醇(3)的三元体系在293.15至333.15 K的9个温度和压力p = 0.1 MPa下的密度(ρ)和粘度(η)的测量二元体系已经在整个组成范围内进行。多余的摩尔体积(V m E)和三元体系的粘度偏差(Δη)已计算并拟合到Nagata-Tamura方程,而二元体系的粘度偏差已计算并拟合到Redlich-Kister方程。从分子相互作用和结构效应的角度讨论了过量的性质和偏离现象。这些基本结果可用于了解混合烃燃料的性质。
更新日期:2018-08-17
中文翻译:
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外-四氢二环戊二烯(1)+甲基环己烷(2)+环丙烷甲醇(3)及其二元三元体系的三元密度和粘度在T = 293.15至333.15 K
外-四氢二环戊二烯(1)+甲基环己烷(2)+环丙烷甲醇(3)的三元体系在293.15至333.15 K的9个温度和压力p = 0.1 MPa下的密度(ρ)和粘度(η)的测量二元体系已经在整个组成范围内进行。多余的摩尔体积(V m E)和三元体系的粘度偏差(Δη)已计算并拟合到Nagata-Tamura方程,而二元体系的粘度偏差已计算并拟合到Redlich-Kister方程。从分子相互作用和结构效应的角度讨论了过量的性质和偏离现象。这些基本结果可用于了解混合烃燃料的性质。