Integrative Photoreduction of CO2 with Subsequent Carbonylation: Photocatalysis for Reductive Functionalization of CO2,ChemSusChem

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Integrative Photoreduction of CO2 with Subsequent Carbonylation: Photocatalysis for Reductive Functionalization of CO2
ChemSusChem ( IF 7.5 ) Pub Date : 2018-08-29 , DOI: 10.1002/cssc.201801621
Xing He ₁ , Yu Cao ₁ , Xian-Dong Lang ₁ , Ning Wang ₁ , Liang-Nian He _{1,

2}

Affiliation

Efficient conversion of CO₂ into fuels and chemicals with solar energy would be promising, but also faces great challenge. In this context, we describe the photoreductive functionalization of CO₂ to construct new C−C, C−N, and C−O bonds through the respective Pd‐catalyzed Suzuki carbonylation, aminocarbonylation, and alkoxycarbonylation of aryl iodides with CO in situ generated through the photoreduction of CO₂. This protocol opens up an alternative avenue for CO₂ utilization by harnessing solar energy.

中文翻译：

集成的光催化还原二氧化碳和随后的羰基化反应：光催化还原功能化的二氧化碳

利用太阳能将CO ₂有效地转化为燃料和化学物质将是有希望的，但同时也面临着巨大的挑战。在这种情况下，我们描述了CO ₂的光还原功能化，通过相应的Pd催化的芳基碘化物的Pd催化的Suzuki羰基化，氨基羰基化和烷氧基羰基化，通过原位生成CO来构建新的C C，C N和C O键。 CO ₂的光还原。该协议通过利用太阳能为CO ₂利用开辟了一条替代途径。

更新日期：2018-08-29

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