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Making Spiroketal‐based Diphosphine (SKP) Ligands via a Catalytic Asymmetric Approach
Chinese Journal of Chemistry ( IF 5.5 ) Pub Date : 2018-07-27 , DOI: 10.1002/cjoc.201800247
Xiaoming Wang 1 , Kuiling Ding 1
Affiliation  

The spiro concept for chiral ligand design represents an important contribution to the area of asymmetric catalysis. Due to the considerable difficulties in the construction of enantiopure all‐carbon spiro backbones, the development of catalytic asymmetric synthesis of chiral spiro structures via short steps is highly valuable. Herein we present our studies on the catalytic asymmetric synthesis of aromatic spiroketals and the corresponding diphosphine (SKP) ligands.

中文翻译:

通过催化不对称方法制备螺环基二膦(SKP)配体

手性配体设计的螺概念代表了对不对称催化领域的重要贡献。由于对映体纯碳全螺环骨架的构建存在相当大的困难,通过短步骤开发手性螺环结构的催化不对称合成非常有价值。本文中,我们介绍了芳香族螺环化合物和相应的二膦(SKP)配体的催化不对称合成的研究。
更新日期:2018-07-27
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