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Synthesis of Multisubstituted Furans via a Catalyst- and Additive-Free Tandem Reaction of Enynones with Sulfinic Acids in Water
Organic Letters ( IF 4.9 ) Pub Date : 2018-07-20 00:00:00 , DOI: 10.1021/acs.orglett.8b01714 Yue Ren 1 , Ling-Guo Meng 1 , Tao Peng 1 , Lei Wang 1, 2
Organic Letters ( IF 4.9 ) Pub Date : 2018-07-20 00:00:00 , DOI: 10.1021/acs.orglett.8b01714 Yue Ren 1 , Ling-Guo Meng 1 , Tao Peng 1 , Lei Wang 1, 2
Affiliation
A facile and efficient tandem reaction of enynones with arylsulfinic acids was developed. A variety of multisubstituted furans were obtained in satisfactory yields via an O2-oxidative single-electron-transfer process without any catalyst and additive in water.
中文翻译:
乙炔酮与亚磺酸在水中的无催化剂和无添加剂串联反应合成多取代基呋喃
开发了一种简便有效的烯酮与芳基亚磺酸的串联反应。经由O 2-氧化单电子转移方法以令人满意的产率获得了多种多取代的呋喃,而在水中没有任何催化剂和添加剂。
更新日期:2018-07-20
中文翻译:
乙炔酮与亚磺酸在水中的无催化剂和无添加剂串联反应合成多取代基呋喃
开发了一种简便有效的烯酮与芳基亚磺酸的串联反应。经由O 2-氧化单电子转移方法以令人满意的产率获得了多种多取代的呋喃,而在水中没有任何催化剂和添加剂。