Synthesis ( IF 2.2 ) Pub Date : 2018-07-16 , DOI: 10.1055/s-0037-1610021
Maxim Uchuskin 1 , Igor Trushkov 2, 3 , Anton Makarov 1
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Abstract
Recent developments on the transformations of furans under oxidative conditions toward the total synthesis of complex natural compounds are discussed. Reactions and methods are classified according to the type of oxidant used. Comparisons are then made between all the strategies to provide a comprehensive overview. This review covers the most prominent work published from 2011 until 2017.
1 Introduction
2 Reagents and Methods for Oxidation of the Furan Ring
2.1 Singlet Oxygen
2.2 Peroxides and Hydroperoxides
2.3 Quinones
2.4 Halogen-Based Oxidants
2.5 Chromium-Based Oxidants
3 The Achmatowicz Reaction
3.1 Halogen-Based Oxidants
3.2 Hydroperoxides
3.3 Enzymatic Oxidation
4 Conclusion
Recent developments on the transformations of furans under oxidative conditions toward the total synthesis of complex natural compounds are discussed. Reactions and methods are classified according to the type of oxidant used. Comparisons are then made between all the strategies to provide a comprehensive overview. This review covers the most prominent work published from 2011 until 2017.
1 Introduction
2 Reagents and Methods for Oxidation of the Furan Ring
2.1 Singlet Oxygen
2.2 Peroxides and Hydroperoxides
2.3 Quinones
2.4 Halogen-Based Oxidants
2.5 Chromium-Based Oxidants
3 The Achmatowicz Reaction
3.1 Halogen-Based Oxidants
3.2 Hydroperoxides
3.3 Enzymatic Oxidation
4 Conclusion
中文翻译：
天然产物全合成中的呋喃氧化反应
摘要
讨论了呋喃在氧化条件下向复杂的天然化合物全合成的转化的最新进展。反应和方法根据所用氧化剂的类型进行分类。然后对所有策略进行比较以提供全面的概述。这篇评论涵盖了从2011年到2017年出版的最杰出的著作。
1引言
2呋喃环氧化的试剂和方法
2.1单重态氧
2.2过氧化物和氢过氧化物
2.3醌
2.4卤素氧化剂
2.5铬基氧化剂
3 Achmatowicz反应
3.1卤素氧化剂
3.2氢过氧化物
3.3酶氧化
4。结论
讨论了呋喃在氧化条件下向复杂的天然化合物全合成的转化的最新进展。反应和方法根据所用氧化剂的类型进行分类。然后对所有策略进行比较以提供全面的概述。这篇评论涵盖了从2011年到2017年出版的最杰出的著作。
1引言
2呋喃环氧化的试剂和方法
2.1单重态氧
2.2过氧化物和氢过氧化物
2.3醌
2.4卤素氧化剂
2.5铬基氧化剂
3 Achmatowicz反应
3.1卤素氧化剂
3.2氢过氧化物
3.3酶氧化
4。结论
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