Synthesis ( IF 2.2 ) Pub Date : 2018-07-16 , DOI: 10.1055/s-0037-1610085 Hyun Kim 1 , Soo Han 1, 2 , Eun Oh 1, 3
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Published as part of the Special Topic Photoredox Methods and their Strategic Applications in Synthesis
Abstract
Trifluoromethylation has emerged as an important tool for modulating the molecular chemical and physical properties in material, polymer, and medicinal chemistry. In particular, photocatalyzed trifluoromethylation in the presence of visible-light irradiation has potentially different activity under mild conditions compared with traditional methods. This review summarizes the recent advances in trifluoromethylation with multiple bond system such as alkynes and alkenes.
1 Introduction
2 Trifluoromethylating Reagents
3 Multicomponent Reactions of Alkynes
4 Multicomponent Reactions of Alkenes
5 Conclusion
Trifluoromethylation has emerged as an important tool for modulating the molecular chemical and physical properties in material, polymer, and medicinal chemistry. In particular, photocatalyzed trifluoromethylation in the presence of visible-light irradiation has potentially different activity under mild conditions compared with traditional methods. This review summarizes the recent advances in trifluoromethylation with multiple bond system such as alkynes and alkenes.
1 Introduction
2 Trifluoromethylating Reagents
3 Multicomponent Reactions of Alkynes
4 Multicomponent Reactions of Alkenes
5 Conclusion
中文翻译：
不饱和碳-碳键可见光催化多组分三氟甲基化的最新进展
作为特别主题的光氧化还原方法及其在合成中的战略应用的一部分发布
抽象的
三氟甲基化已成为调节材料，聚合物和药物化学中分子化学和物理性质的重要工具。特别地，与传统方法相比，在温和条件下在可见光照射下光催化的三氟甲基化具有潜在的不同活性。这篇综述总结了三氟甲基化与多键系统（如炔烃和烯烃）的最新进展。
1引言
2三氟甲基化试剂
3炔烃的多组分反应
4烯烃的多组分反应
5结论
三氟甲基化已成为调节材料，聚合物和药物化学中分子化学和物理性质的重要工具。特别地，与传统方法相比，在温和条件下在可见光照射下光催化的三氟甲基化具有潜在的不同活性。这篇综述总结了三氟甲基化与多键系统（如炔烃和烯烃）的最新进展。
1引言
2三氟甲基化试剂
3炔烃的多组分反应
4烯烃的多组分反应
5结论
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