Synthesis ( IF 2.2 ) Pub Date : 2018-07-04 , DOI: 10.1055/s-0037-1610039
Jian-Ping Zou 1 , Wei Zhang 2 , Cheng-Kun Li 1 , Dong-Liang Zhang 1 , Ogundipe Olamiji 1 , Pei-Zhi Zhang 1 , Adedamola Shoberu 1
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Published as part of the Special Topic Modern Radical Methods and their Strategic Applications in Synthesis
Abstract
Mn(OAc)3-mediated alkoxycarbonylation of indoles, pyrimidinones, and pyridinones with alkyl carbazates is reported. The reactions proceed through a radical process to afford regioselectively 3-carboxylated indoles, 5-carboxylated pyrimidinones, and 3-carboxylated pyridinones in moderate to good yields under mild reaction conditions.
Mn(OAc)3-mediated alkoxycarbonylation of indoles, pyrimidinones, and pyridinones with alkyl carbazates is reported. The reactions proceed through a radical process to afford regioselectively 3-carboxylated indoles, 5-carboxylated pyrimidinones, and 3-carboxylated pyridinones in moderate to good yields under mild reaction conditions.
中文翻译:
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Mn(OAc)3介导的吲哚,嘧啶酮和吡啶酮的区域选择性自由基烷氧羰基化
作为特别主题“现代自由基方法及其在合成中的战略应用”的一部分发布
抽象的
Mn(OAc)3介导的吲哚,嘧啶酮和吡啶酮与烷基咔唑的烷氧基羰基化反应。反应通过自由基过程进行,以在温和的反应条件下以中等至良好的产率提供区域选择性的3-羧化吲哚,5-羧化嘧啶酮和3-羧化吡啶酮。
Mn(OAc)3介导的吲哚,嘧啶酮和吡啶酮与烷基咔唑的烷氧基羰基化反应。反应通过自由基过程进行,以在温和的反应条件下以中等至良好的产率提供区域选择性的3-羧化吲哚,5-羧化嘧啶酮和3-羧化吡啶酮。