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Aromatization of (Z) and (E)-α-atlantones isolated from Cedrus atlantica essential oil followed by condensation with thiosemicarbazide: synthesis of new thiadiazolines derivatives
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2015-12-31 02:49:23
Noureddine Mazoir, Mohamed Dakir, Mohamed Tebbaa, Mohamed Loughzail, Ahmed Benharref

Aromatization, using Pd/C (10%) of (Z) and (E)-α-atlantones isolated from Cedrus atlantica essential oil, followed by condensation with thiosemicarbazide gave novel 1,3,4-thiadiazolic derivatives by the introduction of new functional groups on the terpenic skeletons. After aromatization and thiosemicarbazide condensation, all products were obtained in good yields to give thiadiazolic compounds bearing new spiro carbons.

中文翻译:

从大西洋雪松精油中分离出的(Z)和(E)-α-Atlantones进行芳香化,然后与thiosemicarbazide缩合:新的噻二唑啉衍生物的合成

芳香化处理,使用从Cedrus atlantica精油中分离的Pd / C(10%)的(Z)和(E)-α-Atlantones,然后与thiosemicarbazide缩合,通过引入新的组在萜骨架上。经过芳构化和硫代氨基脲缩合后,所有产物均以高收率获得,从而得到带有新螺碳的噻二唑化合物。
更新日期:2015-12-31
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