Reactions and Polymerizations at the Liquid–Liquid Interface,Chemical Reviews

当前位置： X-MOL 学术 › Chem. Rev. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Reactions and Polymerizations at the Liquid–Liquid Interface
Chemical Reviews ( IF 51.4 ) Pub Date : 2015-12-28 00:00:00 , DOI: 10.1021/acs.chemrev.5b00567
Keti Piradashvili ₁ , Evandro M. Alexandrino ₁ , Frederik R. Wurm ₁ , Katharina Landfester ₁

Affiliation

Reactions and polymerizations at the interface of two immiscible liquids are reviewed. The confinement of two reactants at the interface to form a new product can be advantageous in terms of improved reaction kinetics, higher yields, and selectivity. The presence of the liquid–liquid interface can accelerate the reaction, or a phase-transfer catalyst is employed to draw the reaction in one phase of choice. Furthermore, the use of immiscible systems, e.g., in emulsions, offers an easy means of efficient product separation and heat dissipation. A general overview on low molecular weight organic chemistry is given, and the applications of heterophase polymerization, occurring at or in proximity of the interface, (mostly) in emulsions are presented. This strategy can be used for the efficient production of nano- and microcarriers for various applications.

中文翻译：

液-液界面处的反应和聚合

审查了两种不混溶液体界面的反应和聚合反应。就改进的反应动力学，更高的产率和选择性而言，将两种反应物限制在界面处以形成新产物是有利的。液-液界面的存在可以加速反应，或者使用相转移催化剂在选择的一个相中进行反应。此外，例如在乳液中使用不混溶的系统提供了有效的产品分离和散热的简便方法。给出了低分子量有机化学的一般概述，并介绍了发生在界面处或界面附近（主要是乳液中）的异相聚合的应用。

更新日期：2015-12-28

点击分享查看原文

点击收藏

公开下载

阅读更多本刊新发论文本刊介绍/投稿指南