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BaLiZn3B3O9: a Mixed‐Cation KBe2BO3F2‐Type Zinc‐Borate with a (LiZn3B3O9)∞ Network
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2018-08-20 , DOI: 10.1002/ejic.201800665
Meihong Duan 1 , Mingjun Xia 2 , Rukang Li 1
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2018-08-20 , DOI: 10.1002/ejic.201800665
Meihong Duan 1 , Mingjun Xia 2 , Rukang Li 1
Affiliation
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The mixed‐cation KBe2BO3F2‐type polyborate, BaLiZn3B3O9, has been obtained. It was constituted by a three‐dimensional (LiZn3B3O9)∞ network with perpendicularly connected (LiZn3B3O16)∞ layers. Within each single layer, a KBe2BO3F2‐type six‐membered ring structure is perfectly maintained. In the structure of BaLiZn3B3O9, the interlayer connection between adjacent (LiZn3B3O16)∞ layers contains not only Ba–O ionic bonds but also Zn‐O covalent bonds, which help to overcome the plate‐like growth nature of KBe2BO3F2‐type polyborates.
中文翻译：
BaLiZn3B3O9：具有（LiZn3B3O9）∞网络的混合阳离子KBe2BO3F2型硼酸锌
已获得混合阳离子KBe 2 BO 3 F 2型多硼酸盐BaLiZn 3 B 3 O 9。它由具有垂直连接的（LiZn 3 B 3 O 16）∞层的三维（LiZn 3 B 3 O 9）∞网络组成。在每个单层中，都完美地保留了KBe 2 BO 3 F 2型六元环结构。BaLiZn 3 B 3 O 9的结构相邻（LiZn之间的层间连接3乙3 ö 16）∞层不仅含有的Ba-O离子键，而且Zn-O类的共价键，以克服其帮助板状的KBE生长性质2 BO 3 ˚F 2 -类型多硼酸盐。
更新日期：2018-08-20
中文翻译：
BaLiZn3B3O9：具有（LiZn3B3O9）∞网络的混合阳离子KBe2BO3F2型硼酸锌
已获得混合阳离子KBe 2 BO 3 F 2型多硼酸盐BaLiZn 3 B 3 O 9。它由具有垂直连接的（LiZn 3 B 3 O 16）∞层的三维（LiZn 3 B 3 O 9）∞网络组成。在每个单层中，都完美地保留了KBe 2 BO 3 F 2型六元环结构。BaLiZn 3 B 3 O 9的结构相邻（LiZn之间的层间连接3乙3 ö 16）∞层不仅含有的Ba-O离子键，而且Zn-O类的共价键，以克服其帮助板状的KBE生长性质2 BO 3 ˚F 2 -类型多硼酸盐。
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