Two series of fluorine-containing fluorenyl anthracenes linked by a rigid sp³-hybridized carbon atom have been synthesized and characterized. The effect of a fluorine auxochrome at different positions in fluorene moiety on bulk properties, such as photophysical, electrochemical properties and thermal stabilities were investigated. The non-doped organic light-emitting diodes (OLEDs) utilizing C9-methylated fluorinated fluorenyl anthracene 4b as the emitter exhibits deep-blue emissions CIE x, y (0.159, 0.106) with efficiency of 1.31 cd/A and a maximum brightness of 2040 cd/m² at 14 V. It was found that the introduction of fluorine auxochrome to the C2 position of fluorene could afford the best performances of OLEDs among the fluorinated materials.

已经合成并表征了通过刚性的sp ^3-杂化碳原子连接的两个系列的含氟芴基蒽。研究了芴部分不同位置的氟辅助色素对本​​体性质（如光物理，电化学性质和热稳定性）的影响。使用C9-甲基化的氟化芴基蒽4b作为发射极的非掺杂有机发光二极管（OLED）表现出深蓝色发射CIE x，y（0.159，0.106），效率为1.31 cd / A，最大亮度为2040在14 V时为cd / m ^2。已发现将氟辅助铬引入芴的C2位可以提供氟化材料中OLED的最佳性能。