An Intramolecular OH···π(arene) Interaction in a BINOL–Phenazine Cocrystal with a “Free” N-Atom,Crystal Growth & Design

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An Intramolecular OH···π(arene) Interaction in a BINOL–Phenazine Cocrystal with a “Free” N-Atom
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2018-06-05 00:00:00 , DOI: 10.1021/acs.cgd.8b00199
Katherine E. Peterson _{1,

2} , Rodger F. Henry ₁ , Geoff G. Z. Zhang ₁ , Leonard R. MacGillivray ₂

Affiliation

We report the occurrence of the hydrogen-bond donor molecule 1,1′-binaphthyl-2,2′-diol (BINOL) that in the presence of the appreciably strong hydrogen-bond acceptor phenazine forms a cocrystal stabilized by weak OH···π(arene) interactions. We also present a survey of the Cambridge Structural Database involving BINOL that reveals a limited number of structures that demonstrate the presence of a hydrogen-bond acceptor group viz-a-viz phenazine that does not participate in a traditional hydrogen bond with BINOL.

中文翻译：

具有“游离” N原子的BINOL-吩嗪共晶体中的分子内OH···π（芳烃）相互作用

我们报道了氢键供体分子1,1'-联萘-2,2'-二醇（BINOL）的出现，该氢键在存在相当强的氢键受体吩嗪的情况下形成了由弱OH···稳定的共晶体。 π（芳烃）相互作用。我们还介绍了涉及BINOL的剑桥结构数据库的一项调查，该调查揭示了数量有限的结构，这些结构表明存在不与BINOL参与传统氢键的氢键受体基团viz-a-viz吩嗪。

更新日期：2018-06-05

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