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Structural Characterization and Identification of Graphdiyne and Graphdiyne-Based Materials
ACS Applied Materials & Interfaces ( IF 8.3 ) Pub Date : 2018-05-30 00:00:00 , DOI: 10.1021/acsami.8b05051
Haihong Bao 1 , Lei Wang 1 , Chao Li 1 , Jun Luo 1
Affiliation  

Graphdiyne (GDY) is a two-dimensional (2D) carbon allotrope consisting of sp2- and sp-hybridized carbon atoms. It and GDY-based materials have tremendous application potentials in the fields of catalysis, energy, sensor, electronics and optoelectronics because of their excellent chemical and physical properties. Thus, the explorations to synthesize high-quality GDY and GDY-based materials and to reveal the relationship between their structures and properties are of significance, in which their structural characterization and identification are a crucial step. In this review, we focus on advanced structural characterization techniques and results on GDY, GDY derivatives, GDY composites and doped GDY, including scanning electron microscope (SEM), transmission electron microscope (TEM), atomic force microscope (AFM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, ultraviolet–visible (UV–vis) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, X-ray absorption spectroscopy (XAS), electron energy loss spectroscopy (EELS), and energy-dispersive X-ray spectroscopy (EDS). This review can provide a systemic understanding of the structural characterization and identification of GDY and GDY-based materials and help their development for high-performance applications.

中文翻译:

石墨二炔和基于石墨二炔的材料的结构表征和鉴定

石墨二炔(GDY)是由sp 2组成的二维(2D)碳同素异形体-和sp杂化的碳原子。它和基于GDY的材料因其优异的化学和物理性能而在催化,能源,传感器,电子和光电领域具有巨大的应用潜力。因此,探索合成高质量的GDY和GDY基材料并揭示其结构与性能之间的关系具有重要意义,其中,对其结构进行表征和鉴定是至关重要的一步。在这篇综述中,我们重点介绍了先进的结构表征技术以及有关GDY,GDY衍生物,GDY复合材料和掺杂GDY的结果,包括扫描电子显微镜(SEM),透射电子显微镜(TEM),原子力显微镜(AFM),拉曼光谱, X射线光电子能谱(XPS),X射线衍射(XRD),傅里叶变换红外(FT-IR)光谱,紫外可见(UV-vis)光谱,核磁共振(NMR)光谱,X射线吸收光谱(XAS),电子能量损失光谱(EELS)和能量色散X射线光谱法(EDS)。这篇综述可以对GDY和基于GDY的材料的结构表征和识别提供系统的理解,并有助于它们在高性能应用中的开发。
更新日期:2018-05-30
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