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A De Novo Approach for the Stereoselective Synthesis of Cyclopenta[c]pyranone Scaffold Present in Iridoids: Formal Syntheses of Isoboonein, Iridomyrmecin and Isoiridomyrmecin
ChemistrySelect ( IF 1.9 ) Pub Date : 2018-05-28 , DOI: 10.1002/slct.201800421
Manvendra Singh Kaurav 1 , Virendra Kumar 1 , Dileep Kumar 1 , Tabrez Khan 1
Affiliation  

A conceptually new intramolecular Pauson‐Khand reaction (IPKR) based general strategy has been demonstrated for the formal syntheses of isoboonein, iridomyrmecin and isoiridomyrmecin from very cheap, commercially available starting material.

中文翻译:

从头合成立体异构体中环戊[c]吡喃酮骨架的立体选择性合成方法:异波酮,异肌红霉素和异阿霉素的正式合成方法

已经证明了一种基于概念上新的分子内Pauson-Khand反应(IPKR)的通用策略,可以从非常便宜的市售原料中正式合成异波宁,异丁香霉素和异丁香霉素。
更新日期:2018-05-28
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