Aromaticity and Antiaromaticity in Zintl Clusters,Chemistry - A European Journal

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Aromaticity and Antiaromaticity in Zintl Clusters
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-07-11 , DOI: 10.1002/chem.201801715
Chao Liu _{1,

2,

3} , Ivan A. Popov ₄ , Zhongfang Chen ₅ , Alexander I. Boldyrev ₆ , Zhong-Ming Sun _{1,

2}

Affiliation

Originally, the concepts of aromaticity and antiaromaticity were introduced to explain the stability and reactivity of unsaturated organic compounds. Since then, they have been extended to other species with delocalized electrons including various saturated systems, organometallic compounds, and even inorganic clusters and molecules. In this Minireview, we focus on the most recent progress of using these concepts to guide experimental synthesis and rationalize geometrical and electronic structures of a particular family of polyanions composed of Group 14 and 15 elements, namely Zintl clusters.

中文翻译：

Zintl簇中的芳香性和抗芳香性

最初，引入芳香性和抗芳香性的概念来解释不饱和有机化合物的稳定性和反应性。从那时起，它们已扩展到具有离域电子的其他物种，包括各种饱和系统，有机金属化合物，甚至无机簇和分子。在此Minireview中，我们重点介绍使用这些概念指导实验合成以及合理化由14和15组元素组成的特定聚阴离子家族（即Zintl团簇）的几何和电子结构的最新进展。

更新日期：2018-07-11

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