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Oxidative C–C Bond Cleavage for the Synthesis of Aryl Carboxylic Acids from Aryl Alkyl Ketones
Synlett ( IF 1.7 ) Pub Date : 2018-05-16 , DOI: 10.1055/s-0037-1609751 Meichao Li 1 , Zhenlu Shen 1 , Liang Xu 1 , Shengpeng Wang 2 , Bajin Chen 2 , Xinquan Hu 1 , Baoxiang Hu 1 , Liqun Jin 1 , Nan Sun 1
Synlett ( IF 1.7 ) Pub Date : 2018-05-16 , DOI: 10.1055/s-0037-1609751 Meichao Li 1 , Zhenlu Shen 1 , Liang Xu 1 , Shengpeng Wang 2 , Bajin Chen 2 , Xinquan Hu 1 , Baoxiang Hu 1 , Liqun Jin 1 , Nan Sun 1
Affiliation
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A metal-free and one-pot two-step synthesis of aryl carboxylic acids from aryl alkyl ketones has been achieved. The reactions were performed with iodine as the catalyst, DMSO and TBHP as the oxidants. Under the optimal reaction conditions, a number of aryl alkyl ketones could be converted into their corresponding aryl carboxylic acids in good to excellent yields (up to 94%).
中文翻译：
用于从芳基烷基酮合成芳基羧酸的氧化 C-C 键裂解
已经实现了从芳基烷基酮无金属和一锅两步合成芳基羧酸。反应以碘为催化剂，DMSO和TBHP为氧化剂。在最佳反应条件下，许多芳基烷基酮可以以良好到极好的收率（高达 94%）转化为其相应的芳基羧酸。
更新日期：2018-05-16
中文翻译：
用于从芳基烷基酮合成芳基羧酸的氧化 C-C 键裂解
已经实现了从芳基烷基酮无金属和一锅两步合成芳基羧酸。反应以碘为催化剂，DMSO和TBHP为氧化剂。在最佳反应条件下，许多芳基烷基酮可以以良好到极好的收率（高达 94%）转化为其相应的芳基羧酸。
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