Isobaric Vapor–Liquid Equilibrium Data for Binary Systems of Anisole with Methyl Acetate, Ethyl Acetate, n-Propyl Acetate, and Isopropyl Acetate at 93.9 kPa,Journal of Chemical & Engineering Data

当前位置： X-MOL 学术 › J. Chem. Eng. Data › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Isobaric Vapor–Liquid Equilibrium Data for Binary Systems of Anisole with Methyl Acetate, Ethyl Acetate, n-Propyl Acetate, and Isopropyl Acetate at 93.9 kPa
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2018-04-23 , DOI: 10.1021/acs.jced.8b00063
Bharat R. Bhoi ₁ , Nilesh A. Mali ₂ , Sunil S. Joshi ₂

Affiliation

The present work reports experimental isobaric vapor–liquid equilibrium data at 93.9 kPa pressure using a dynamic recirculation still for four binary pairs of acetates with anisole. The suitability of the experimental data for modeling was established by performing the Herington area test, Van Ness test, and mean absolute deviation test. Binary interaction parameters necessary for process modeling were derived through the regression of the VLE data for Wilson, NRTL, and UNIQUAC activity coefficient models with a suitable objective function. VLE data in the form of T–x, y plots indicates no formation of azeotropes for all pairs.

中文翻译：

苯甲醚与乙酸甲酯，乙酸乙酯，乙酸正丙酯和乙酸异丙酯的二元系统等压蒸气-液体平衡数据，在93.9 kPa时

目前的工作报告了在动态压力下，仍然动态地对四对二元对的乙酸与苯甲醚进行的乙酸盐在93.9 kPa压力下的等压蒸气-液体平衡实验数据。通过执行Herington区域检验，Van Ness检验和平均绝对偏差检验来确定实验数据是否适合建模。通过具有适当目标函数的Wilson，NRTL和UNIQUAC活动系数模型的VLE数据回归，可以得出过程建模所需的二元相互作用参数。VLE数据以T – x，y的形式表示，所有对均没有形成共沸物。

更新日期：2018-04-23

点击分享查看原文

点击收藏

阅读更多本刊新发论文