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Nd(OTf)3-catalyzed intramolecular-intermolecular cascade cyclization reaction: An access to phenanthro[9,10-b]furan derivatives
Journal of Saudi Chemical Society ( IF 5.8 ) Pub Date : 2019-06-12 , DOI: 10.1016/j.jscs.2019.05.010
Hao Dong , Dawen Xu , Wangsheng Liu , Yaopeng Zhang , Hao Guo

An intramolecular-intermolecular cascade cyclization reaction via multi metal-carbene intermediates has been developed. This reaction uses catalytic amount of Nd(OTf)3, which actives both alkyne and aldehyde moieties. This protocol provides a novel strategy for the synthesis of phenanthro[9,10-b]furans.



中文翻译:

Nd(OTf)3催化的分子内分子间级联环化反应:菲[9,10- b ]呋喃衍生物的获得途径

已经开发了通过多种金属-卡宾中间体的分子内-分子间级联环化反应。该反应使用催化量的Nd(OTf)3,该酶同时激活炔烃和醛基。该方案为合成菲咯啉[9,10- b ]呋喃提供了一种新颖的策略。

更新日期:2019-06-12
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