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Synthesis and material properties of elastomeric high molecular weight polycycloacetals derived from diglycerol and meso‐erythritol
Journal of Applied Polymer Science ( IF 2.7 ) Pub Date : 2019-12-09 , DOI: 10.1002/app.48780 Ariah C. Law 1 , Dakota S. Stankowski 1 , Blake H. Bomann 2 , Shanzay Suhail 2 , Kyle H. Salmon 1 , Samuel W. Paulson 1 , Michael J. Carney 2 , Nicholas J. Robertson 1
Journal of Applied Polymer Science ( IF 2.7 ) Pub Date : 2019-12-09 , DOI: 10.1002/app.48780 Ariah C. Law 1 , Dakota S. Stankowski 1 , Blake H. Bomann 2 , Shanzay Suhail 2 , Kyle H. Salmon 1 , Samuel W. Paulson 1 , Michael J. Carney 2 , Nicholas J. Robertson 1
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Copolymerizing glutaraldehyde with tetraols such as diglycerol, meso‐erythritol, and pentaerythritol is particularly effective for forming very high molecular weight polycycloacetals (Mn up to 65,000 g/mol) with elastomeric properties and up to 70% biorenewable content by weight. Altering the tetraol monomer feed ratio provides control over the polycycloacetal's tensile properties. The polymerizations are high‐yielding, readily scalable, and employ commercially available starting materials that are used without further purification. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48780.
中文翻译：
由甘油和中赤藓糖醇衍生的弹性体高分子量聚环缩醛的合成及材料性能
共聚用戊二醛四醇如双甘油，内消旋-赤藓醇，季戊四醇是特别有效的用于形成非常高的分子量polycycloacetals（中号Ñ多达65,000克/摩尔）与弹性体特性和按重量计至多70％的生物可再生的内容。改变四醇单体的进料比例可控制聚环缩醛的拉伸性能。聚合反应的收率高，易于扩展，并使用可商购的起始原料，无需进一步纯化即可使用。分级为4 +©2019 Wiley Periodicals，Inc.J.Appl。Polym。科学 2020，137，48780。
更新日期：2020-03-09
中文翻译：
由甘油和中赤藓糖醇衍生的弹性体高分子量聚环缩醛的合成及材料性能
共聚用戊二醛四醇如双甘油，内消旋-赤藓醇，季戊四醇是特别有效的用于形成非常高的分子量polycycloacetals（中号Ñ多达65,000克/摩尔）与弹性体特性和按重量计至多70％的生物可再生的内容。改变四醇单体的进料比例可控制聚环缩醛的拉伸性能。聚合反应的收率高，易于扩展，并使用可商购的起始原料，无需进一步纯化即可使用。分级为4 +©2019 Wiley Periodicals，Inc.J.Appl。Polym。科学 2020，137，48780。
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