Preparation and Catalytic Activity of Novel σ,π‐Dual Gold(I) Acetylide Complexes,European Journal of Organic Chemistry

当前位置： X-MOL 学术 › Eur. J. Org. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Preparation and Catalytic Activity of Novel σ,π‐Dual Gold(I) Acetylide Complexes
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2019-12-23 , DOI: 10.1002/ejoc.201901623
Huey-San Melanie Siah ₁ , Anne Fiksdahl ₁

Affiliation

Chiral bridged σ,π‐dual gold(I)‐acetylide complexes were synthesised, characterised, and their catalytic activity was investigated. Dual gold(I)‐catalysed reactions of propargylic alcohol derivatives show different catalytic potential than the monogold or digold complexes. Mechanistic explanations are proposed for the differing regioselectivity or the similar or higher enantioselective outcome of some reactions.