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Diverse One-Pot Electrophilic Trapping Reactions of 2-Quinolylzincates with Acyl Chlorides and Allyl Iodide
Synthesis ( IF 2.2 ) Pub Date : 2019-11-21 , DOI: 10.1055/s-0039-1690036 Hye Jin Jeong 1 , Suyeon Chae 1 , Keunhong Jeong 2 , Sung Keon Namgoong 1
Synthesis ( IF 2.2 ) Pub Date : 2019-11-21 , DOI: 10.1055/s-0039-1690036 Hye Jin Jeong 1 , Suyeon Chae 1 , Keunhong Jeong 2 , Sung Keon Namgoong 1
Affiliation
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The tandem acylation reactions of 2-quinolylzincates under one-pot reaction conditions facilitated the formation of biologically active (Z)-3-alkylidenephthalides and multifunctionalized quinoline derivatives at specific positions. The reactions of these zincates with allyl iodide produced three different types of temperature- and alkyl-ligand-dependent C-2 homologated quinolines. The reaction mechanisms for the formation of the presented products from 2-quinolylzincates are also proposed in detail.
中文翻译：
2-喹啉锌酸酯与酰基氯和烯丙基碘的单电位亲电陷阱反应
在一锅法反应条件下，2-喹啉基锌酸酯的串联酰化反应有助于在特定位置形成生物活性的（Z）-3-亚烷基萘和多官能化喹啉衍生物。这些锌酸盐与烯丙基碘的反应产生了三种不同类型的依赖温度和烷基配体的C-2同源喹啉。还详细提出了由2-喹啉基锌酸酯形成所提出的产物的反应机理。
更新日期：2019-11-22
中文翻译：
2-喹啉锌酸酯与酰基氯和烯丙基碘的单电位亲电陷阱反应
在一锅法反应条件下，2-喹啉基锌酸酯的串联酰化反应有助于在特定位置形成生物活性的（Z）-3-亚烷基萘和多官能化喹啉衍生物。这些锌酸盐与烯丙基碘的反应产生了三种不同类型的依赖温度和烷基配体的C-2同源喹啉。还详细提出了由2-喹啉基锌酸酯形成所提出的产物的反应机理。
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